E' di una semplicità DISARMANTE
ecco l'esempio che mette lui
Codice PHP:
<?php
require("class.phpmailer.php");

$mail = new PHPMailer();

$mail->IsSMTP();                                   // send via SMTP
$mail->Host     "smtp1.site.com;smtp2.site.com"// SMTP servers
$mail->SMTPAuth true;     // turn on SMTP authentication
$mail->Username "jswan";  // SMTP username
$mail->Password "secret"// SMTP password

$mail->From     "from@email.com";
$mail->FromName "Mailer";
$mail->AddAddress("josh@site.com","Josh Adams"); 
$mail->AddAddress("ellen@site.com");               // optional name
$mail->AddReplyTo("info@site.com","Information");

$mail->WordWrap 50;                              // set word wrap
$mail->AddAttachment("/var/tmp/file.tar.gz");      // attachment
$mail->AddAttachment("/tmp/image.jpg""new.jpg"); 
$mail->IsHTML(true);                               // send as HTML

$mail->Subject  =  "Here is the subject";
$mail->Body     =  "This is the [b]HTML body[/b]";
$mail->AltBody  =  "This is the text-only body";

if(!
$mail->Send())
{
   echo 
"Message was not sent 

"
;
   echo 
"Mailer Error: " $mail->ErrorInfo;
   exit;
}

echo 
"Message has been sent";
Credo quasi si spieghi da solo no?