È già scritto nel file di configurazione...
basta leggere la documentazione

# You may restrict local users to their home directories. See the FAQ for
# the possible risks in this before using chroot_local_user or
# chroot_list_enable below.
chroot_local_user=YES
#
# You may specify an explicit list of local users to chroot() to their home
# directory. If chroot_local_user is YES, then this list becomes a list of
# users to NOT chroot().
chroot_list_enable=YES
# (default follows)
chroot_list_file=/etc/vsftpd.chroot_list